Tutorial 1 - Simple Atomic Structure

 

Constituents of the Atom

The simplest model of the atom is shown in the diagram below:

This is the layout of a lithium atom, with three protons, three electrons, and four neutrons.  The protons and neutrons are, of course, found in the nucleus.  They are called nucleons.  The electrons are found in shells orbiting the nucleus.

Question 1

 How many protons neutrons and electrons are there in the lithium atom? 

Answer

  It is important to understand:

 

Property

Electron

Proton

Neutron

Charge

-1 e

+1 e

0

Mass

9.11 × 10-31 kg

1.67 × 10-27 kg

1.67 × 10-27 kg

Relative Mass

1/1836

1.0000

1.0004

  Notice that:

Question 2

A carbon atom has 6 protons and 6 neutrons.  Draw out the carbon atom in a similar way to the lithium atom in the diagram above. Answer

Question 3

What is the total charge of a carbon nucleus?

(a) in electronic charge units

(b) in coulombs

 Answer

Question 4

What is the total charge of the electrons?

(a) in electronic charge units

(b) in coulombs

Answer

 

Charged Atoms

Atoms are neutral because the positive charge and the negative charge cancel out.  If an electron is removed, the atom becomes positively charged and we call the charged atom an ion.  If an electron is added, we get a negative ion.  The protons never move.

The movement of electrons between atoms is at the heart of chemical reactions.

 

Isotopes

Different atoms are distinguished by their numbers of protons and neutrons.  We write the symbols using the following notation:

Be careful not to confuse atomic number with the symbol A.  We will refer to A as the nucleon number in these notes and Z as the proton number.

We can determine the number of neutrons simply by subtracting the proton number from the nucleon number. 

No of neutrons = A – Z

Atomic particles are always in whole numbers.

Chemical reactions involve the electrons of the outer shells.  Nuclei are not involved in any way, and remain totally unaltered even in the fiercest chemical reactions.

Question 5 

 Carbon 14 is an isotope of Carbon.  Complete the table:

Protons                                           

 

 

Neutrons                                        

 

 

Electrons                                       

 

 

Write out carbon-14 in isotope form                                                           

 

Answer

Carbon-14 looks like this:

 

 

 

 

 

 

 

 

 

 

 

Carbon 14 is an unstable isotope.  It decays so that one of the neutrons turns into a proton.

Question 6

Can you draw out the new atom?  How many protons, neutrons and electrons does it have?  What is it?

Answer

 

Charge to mass ratio

This is an important quantity to particle physicists.  If two particles have the same charge to mass ratio, they will be deflected by the same amount by magnetic fields or electric fields (you will study these at A2).

The charge to mass ratio is given by this equation:

Charge to mass ratio = charge (C) ÷ mass (kg)

Charge to mass ratio = q

                              m

The units are coulombs per kilogram (C kg-1)

The electron has the highest charge to mass ratio, as it's the smallest particle.  For an electron, the calculation is quite simple:

 Charge to mass ratio = 1.6 × 10-19 C ÷ 9.11 × 10-31 kg = 1.76 × 1011 C kg-1

For a nucleus (without the electrons) we have to be a bit more careful, as shown in the worked example:

Worked Example

What is the charge to mass ratio of a helium nucleus (alpha particle)?

We will assume that the proton and the neutrons have the same mass, 1.67 × 10-27 kg.

 

In a helium nucleus, there are 2 protons and 2 neutrons, making up 4 nucleons.

 

Charge to mass ratio = 2 × 1.6 × 10-19 C

                              4 × 1.67 × 10-27 kg

                           = 4.85 × 107 C kg-1

 

For a neutral atom, the charge to mass ratio is zero, because there is no charge.

For the Lithium ion, Li+, there is a charge of 1.6 × 10-19 C.  There are 7 nucleons (3 protons, and 4 neutrons). 

Charge to mass ratio = 1 × 1.6 × 10-19 C    = 1.37 × 107 C kg-1

                               7 × 1.67 × 10-27 kg

 In the exam, read the question carefully.  Make sure that you are doing a charge to mass ratio, not the charge on the ion.  Specific charge is the same thing as the charge to mass ratio.  The unit for charge to mass is C kg-1 not N kg-1.

 

Question 7

A sulphur atom has a nucleon number of 32.  What is the specific charge of an S2- ion?

Mass of a nucleon = 1.67 × 10-27 kg; e = 1.6 × 10-19 C.

Answer

 
 
Rutherford Scattering

In the early part of the last century, the accepted model of the atom was proposed by J J Thompson in his plum pudding model.  This consisted of a matrix of protons in which were embedded electrons.  Although this may sound ridiculous today, scientists previously believed that the atom could not be broken down at all.

Ernest Rutherford (1871 – 1937) used alpha particles to study the nature of atomic structure with the following apparatus:

Rutherford was using alpha particles (helium nuclei) as nuclear bullets to smash up the atoms; he wanted to see atoms bursting like watermelons.  But…

  His observations are best illustrated with this diagram

Instead of bits of atom, Rutherford found that a small proportion of the alpha particles were deflected, while an even smaller proportion bounced right back.  From analysis of these observations he concluded:

Rutherford’s estimates were not far out.  Later research has shown the nuclear radius to be in the order of 1.5 × 10-14 m.  However the boundary is not sharp, but rather fuzzy, as the nucleus is very dynamic.

Question 8

What led Rutherford to conclude that the nucleus was very tiny and had a positive charge? 

Answer